Slushiust_revision_chemistry

Physical properties

and also the types of bonding


Ionic substances

Structure and Bonding

Ionic substances are made of oppositely charged ions arranged in a 3D crystal lattice. There is a strong electrostatic force of attraction between the oppositely charged ions.


Melting and Boiling Point

Because there is a strong electrostatic force of attraction between the charged ions, a high amount of energy will be required to overcome these forces of attraction. This gives ionic compounds a high melting & boiling point.


Brittleness

When force is applied on the crystal lattice, the lattice can shaters if two like-charges come across each other, causing them to repel and break the structure


Solubility

Oppositely charged ions get attracted to the partial negative and postive ends of the polar water molecule. Solute-solvent attractions are strong enough to overcome solute-solute and solvent-solvent attractions.


Electricity

Electricity is the flow of charge. In ionic bonds, this is not electrons it is the ions. Ionic substances are able to conduct electricity in liquid/molten/aqueous states as the charges are free to move around and carry charge.


melting/boiling point: high

malleable: no

ductile: no

brittle: yes

electrically conductive: only when liquid

thermally conductive: no*


* - for the exam they want us to say no but in reality it's much more complicated idk


Metallic substances

Structure and Bonding

Metal cations (positive) are electrically attracted to the 'sea' of delocalised electrons, forming a non-directional metallic bond.


Hardness

A lot of external force is needed to overcome the strong metallic bond to wear metal cations away from the structure.


Thermal/electrically conductive

The closely packed ions allow efficient collision between metal ions. Also the free-moving electrons gain Ek and enchance the collsion to transfer heat.


Malleablility and Ductility

The metallic bond is non-directional, so when external forces are applied the layers of metal ions can slide across each other without breaking the bond.


melting/boiling point: high

malleable: yes

ductile: yes

brittle: no

electrically conductive: yes

thermally conductive: yes


Simple Molecular substances

Structure and Bonding

Atoms are covalently bonded (able to share electrons) with each other to form a molecule. These molecules interact with each other via weak intermolecular forces.


Melting/Boiling point

Only a small amount of heat energy is needed to overcome the weak intermolecular forces.


Thermal and Electrical conductivity

The distance between molecules is far away. The makes the collisions between particles very inefficient and thus not allowing charge or heat to transfer.


Solubulity

The electrostatic force holding the ion in substances like NaCl (ionic substances) will be overcome in water due to fact that solute-solvent bonds overcome solute-solute and solvent-solvent bonds.

melting/boiling point: low

malleable: no

ductile: no

brittle: sometimes (doesnt matter lol)

electrically conductive: no

thermally conductive: no


talking about molecular substances, carbon chains also exist and will likely show up so here's my chance to yap about them.


Carbon chains and such

Carbon chains are awesome! But to be more specific, carbon chains are pretty much just carbon atoms bonding with other carbon atoms within a molecule. Carbon can bond in different way and depending on these ways that it's bonded, itwill act differently. This is called an allotrope. For example take diamonds and graphite. Both are 3D crystal lattices made entirely out of carbon atoms but act very different due to how the atoms are bonded.

Diamonds are one of the toughest materials, this is due to how the carbon atoms are bonded with each other inside the structure. The carbon atoms in diamonds are covalently bonded in a tetrahedral arrangement. Each carbon atom is bonded to 4 other carbon atoms (the same amount as it has valance electrons) allowing each atom to be locked into place by the other atom's bonds

Graphite, howeverm is quite different. Each carbon atom in graphite is bonded to 3 other carbon atoms, with an extra valance electron free and not bonded to another atom (probably not relevant in the test but it's fun to know). Graphite is made out of multiple layers of the carbon atoms arranged in hexagonal formation. These are called graphene. Because the bonds between layers of graphene are weak, they can easily side past each other. This also means that the bonds between layers of graphene are easily broken. Because graphite has each carbon atom bonded to 3 other atoms, it has a valance electron not shared in the covalent bonds, meaning it is delocalised allowing it to be electrically conductive and able to transfer charge throughout the graphite.